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Atomic structure and bonding
JAMB Chemistry topic guide with 2 practice questions.
What to revise
- atoms, molecules and ions; the work of Dalton, Millikan, Rutherford, Moseley, Thomson and Bohr
- atomic structure: four quantum numbers, arrangement of electrons in orbitals, electron configuration, atomic number, mass number, isotopes (elements of atomic number 1-20)
- shapes of s and p orbitals
- the periodic table and periodicity: alkali and alkaline-earth metals, halogens, noble gases, transition metals; variation of ionization energy, ionic radii, electron affinity, electronegativity, electrical and thermal conductivity
- chemical bonding: electrovalency and covalency; hydrogen and metallic bonding; coordinate bond (e.g. [Fe(CN)6]3-, [Fe(CN)6]4-, [Cu(NH3)4]2+, [Ag(NH3)2]+); van der Waals forces
- shapes of simple molecules: linear (H2, O2, Cl2, HCl, CO2), non-linear (H2O), tetrahedral (CH4), pyramidal (NH3)
You should be able to
- distinguish between atoms, molecules and ions
- identify the contributions of these scientists to atomic structure
- deduce the number of protons, neutrons and electrons from atomic and mass numbers
- apply the rules guiding the arrangement of electrons in an atom
- identify common elements exhibiting isotopy and relate isotopy to mass number
- perform simple calculations relating to isotopy
- differentiate between the shapes of the orbitals
- determine the number of electrons in s and p orbitals
- relate atomic number to the position of an element on the periodic table
- relate properties of groups of elements on the periodic table
- identify reasons for variation in properties across the period and down the groups
- differentiate between the types of bonding
- deduce bond types based on electron configurations
- relate the nature of bonding to properties of compounds
- differentiate between the various shapes of molecules
From JAMB's Chemistry syllabus official. Full syllabus →
eZine's published bank has 20 questions on this topic (counted 29 October 2026).
Practice questions
Question 1 · Atomic structure and bonding
Millikan's oil-drop experiment was used to determine
Show answer and explanation
Answer: D. the charge on an electron
By balancing charged oil drops in an electric field, Millikan found that all charges were whole multiples of 1.6 × 10⁻¹⁹ C, the charge on one electron. The charge-to-mass ratio came earlier from Thomson's cathode-ray work; atomic number came from Moseley; the proton's mass was not measured in this experiment.
eZine practice question (original, teacher-reviewed)
Question 2 · Atomic structure and bonding
The line spectrum of hydrogen is best explained by Bohr's idea that
Show answer and explanation
Answer: D. electrons occupy definite energy levels and emit energy only on moving between them
Because energy levels are fixed, a jump between two levels releases a fixed quantum of energy, giving a line of one particular frequency. A uniform positive sphere (Thomson) predicts no lines; light in a spectrum comes from electrons, not the nucleus; Dalton's indivisible atom cannot explain spectra at all.
eZine practice question (original, teacher-reviewed)
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